Issue 0, 1972

Reaction of phenylacetonitrile anion with sulphites: a novel isothiazole synthesis

Abstract

4,5-Diphenylisothiazol-3-ol has been prepared by reaction of phenylacetonitrile anion with sulphites. A tentative mechanism is proposed for the reaction. α-Cyano-α-(4,5-diphenylisothiazol-3-yl)benzyl phenyl thione (IV) and 4-imino-2,3,5-triphenylhex-2-enedinitrile (V) were also isolated from the reaction mixtures.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1972, 1432-1434

Reaction of phenylacetonitrile anion with sulphites: a novel isothiazole synthesis

M. D. Scott, J. Chem. Soc., Perkin Trans. 1, 1972, 1432 DOI: 10.1039/P19720001432

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