(–)-Pin-2(10)-ene reacts with iodine to give 7,8-di-iodo-p-menth-1-ene (II). The latter, on treatment with di-methyl sulphoxide, gives p-mentha-1,4(8)-dien-7-al (V), an isomer of p-mentha-1,8-dien-7-al (perillaldehyde)(I).
D. H. R. Barton, I. A. Blair and P. D. Magnus, J. Chem. Soc., Perkin Trans. 1, 1972, 614 DOI: 10.1039/P19720000614
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