Issue 0, 1972

Optical rotatory dispersion and circular dichroism data for some epicamphor derivatives

Abstract

O.r.d. and c.d. data are reported for the epimeric 2-phenyl and 2-hydroxy-2-phenyl derivatives of (–)-bornan-3-one. The observed contributions of the endo-phenyl and the exo-hydroxy-group to the amplitude or the Δε value are in an opposite sense to that predicted for alkyl groups by the Octant Rule, whereas the exo-phenyl and the endo-hydroxy-group give contributions as predicted by the Octant Rule.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1972, 351-352

Optical rotatory dispersion and circular dichroism data for some epicamphor derivatives

R. F. J. Cole, J. M. Coxon and M. P. Hartshorn, J. Chem. Soc., Perkin Trans. 1, 1972, 351 DOI: 10.1039/P19720000351

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