The synthesis, by conventional methods, of six diastereoisomeric oligopeptides of γ-t-butyl glutamate and the polymerisation of five of them, by means of dicyclohexylcarbodi-imide in acetonitrile, are described. The resulting sequential diastereoisomeric poly-(γ-t-butyl glutamate)s had molecular weights in the range 6500–42,000.
D. I. Marlborough and H. N. Rydon, J. Chem. Soc., Perkin Trans. 1, 1972, 1 DOI: 10.1039/P19720000001
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