Measurements on the emission of the mercury resonance line at 253.7 nm from active nitrogen containing measured amounts of mercury vapour confirm that Hg(63P1) is excited predominantly by N2(A3Σ+u) which is formed in approximately half the three body recombinations of ground state nitrogen atoms with M = N2 or Ar. Rate coefficients are given for some processes removing N2(A).
B. A. Thrush and A. H. Wild, J. Chem. Soc., Faraday Trans. 2, 1972, 68, 2023 DOI: 10.1039/F29726802023
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