The ultra-violet absorption spectra of nitroguanidine is tentatively assigned on the basis of a VESCF CI MO calculation of its singlet excited states. Its absorption envelope is attributed to σ, π, and “lone-pair” electron transitions. The application of the results to other conjugated nitramines is discussed and the spectra of conjugated and unconjugated nitramines are compared.
J. Stals and M. G. Pitt, J. Chem. Soc., Faraday Trans. 2, 1972, 68, 1659 DOI: 10.1039/F29726801659
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