Issue 0, 1972

Raman spectral study of bisulphate ion hydration

Abstract

Raman spectra of solutions of H2SO4, NH4HSO4 and LiHSO4 over a wide concentration range, were obtained. Pronounced asymmetry was found in the 1050 cm–1 bisulphate ion line for all solutions more dilute than 6 M. Analysis of the data, using a minimum of assumptions yields an interpretation of the spectra which differs in several respects from previous ones, and suggests that two differently hydrated forms of the HSO4 ion exist.

Article information

Article type
Paper

J. Chem. Soc., Faraday Trans. 2, 1972,68, 643-648

Raman spectral study of bisulphate ion hydration

D. J. Turner, J. Chem. Soc., Faraday Trans. 2, 1972, 68, 643 DOI: 10.1039/F29726800643

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