The photoelectron spectra of the pseudohalides RQ (R ![[double bond, length as m-dash]](https://www.rsc.org/images/entities/char_e001.gif)
H, CH3, SiH3, GeH3, Me3Si; Q NCO, NCS, N3) have been recorded. The spectra provide a basis for semi-quantitative discussions of structure and bonding in these compounds, and are consistent with the occurrence of (π→d)π-bonding in the silicon and germanium compounds.
S. Cradock, E. A. V. Ebsworth and J. D. Murdoch, J. Chem. Soc., Faraday Trans. 2, 1972, 68, 86 DOI: 10.1039/F29726800086
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