A non-linear least squares method is described for analyzing kinetic data to obtain the rate constant for a first-order reaction where the initial and final readings are unknown. One advantage over Guggenheim's and similar methods is that readings do not have to be taken at constant time intervals.
P. Moore, J. Chem. Soc., Faraday Trans. 1, 1972, 68, 1890 DOI: 10.1039/F19726801890
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