Issue 0, 1972
From the journal:

Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases

Free radical addition to olefins. Part 9.—Addition of methyl radicals to fluoro-ethylenes

J. M. Tedder,   J. C. Walton  and  K. D. R. Winton  

Abstract

A method to determine the relative rate of addition of methyl radicals to each end of a series of fluoroethylenes has been developed and the following differences (Δ) in activation parameters determined. CH3·+ RCH[double bond, length as m-dash]CH2[graphic omitted]CH3CH2ĊHR [graphic omitted] These figures show considerably different trends to those observed for the addition of trichloromethyl and heptafluoropropyl radicals to the same olefins.

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Article information

DOI
https://doi.org/10.1039/F19726801866
Article type
Paper

J. Chem. Soc., Faraday Trans. 1, 1972,68, 1866-1873

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Free radical addition to olefins. Part 9.—Addition of methyl radicals to fluoro-ethylenes

J. M. Tedder, J. C. Walton and K. D. R. Winton, J. Chem. Soc., Faraday Trans. 1, 1972, 68, 1866 DOI: 10.1039/F19726801866

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