Issue 0, 1972

Arrhenius parameters of the reaction CH3·+ C2H6→ CH4+ C2H5·

Abstract

Study of ethane pyrolysis over the ranges 920–1040 K and 0–200 Torr in a flow system allows evaluation of Arrhenius parameters for the reactions C2H6→ 2CH3·(1), CH3·+ C2H6→ CH4+ C2H5·(2) The results obtained are, log(A1/s–1)= 16.7, E1= 370 kJ mol–1, in close agreement with recent measurements, and log(A2/l. mol–1 s–1)= 11.7 ± 1.0, E2= 90 ± 20 kJ mol–1. The latter values conflict with estimates based on low temperature studies but are consistent with pyrolytic estimates for comparable reactions. It is shown that all available data for k2 fall on a common curve indicating that the relevant Arrhenius parameters are strongly temperature dependent. The origin of this behaviour is briefly discussed and its probable generality for metathetical reactions of alkyl radicals is indicated.

Discrepancies in the balance of methane and n-butane yields are shown to be explicable on the grounds of the occurrence of the minor, primary reaction H + C2H5·→ 2CH3·(7) which proceeds at a rate comparable with chain termination processes.

Article information

Article type
Paper

J. Chem. Soc., Faraday Trans. 1, 1972,68, 1462-1473

Arrhenius parameters of the reaction CH3·+ C2H6→ CH4+ C2H5·

P. D. Pacey and J. H. Purnell, J. Chem. Soc., Faraday Trans. 1, 1972, 68, 1462 DOI: 10.1039/F19726801462

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements