Issue 0, 1972
From the journal:

Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases

Addition of formaldehyde to slowly reacting hydrogen + oxygen mixtures

R. R. Baldwin,   A. R. Fuller,   D. Longthorn  and  R. W. Walker  

Abstract

The effect of HCHO in reducing the induction periods of H2+ O2+ N2 mixtures at 500°C has been examined for a range of mixture composition, using HCHO concentrations in the range 0.05–1.0 %. Computer treatment shows that the marked reduction can only be accounted for by the reaction HO2+ HCHO = H2O2+ HCO(24). A detailed computer analysis of the results for a range of mixtures gives the ratio k24/k½10= 23 (mol l.–1 s)–½. Taking k10(HO2+ HO2= H2O2+ O2)= 1.8 × 109 gives k24= 9.6 × 105 l.mol–1 s–1. With A24= 109, this corresponds to E24= 10.7 kcal mol–1.

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Article information

DOI
https://doi.org/10.1039/F19726801362
Article type
Paper

J. Chem. Soc., Faraday Trans. 1, 1972,68, 1362-1367

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Addition of formaldehyde to slowly reacting hydrogen + oxygen mixtures

R. R. Baldwin, A. R. Fuller, D. Longthorn and R. W. Walker, J. Chem. Soc., Faraday Trans. 1, 1972, 68, 1362 DOI: 10.1039/F19726801362

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