Issue 23, 1972
From the journal:

Journal of the Chemical Society, Dalton Transactions

Cationic transition metal complexes. Part IV. Molybdenum and tungsten dinitrosyl complexes

M. Green  and  Susan H. Taylor  

Abstract

Treatment of [Mo(MeCN)3(CO)3] with NOPF6–MeCN gives cis-[Mo(NO)2(MeCN)4]2+[PF6–]2, (I). The corresponding reaction of [W(MeCN)3(CO)3] affords cis-[W(NO)2(CO)(MeCN)3]2+[PF6–]2, (III). Reaction of (I) and (III) with sodium diethyldithiocarbamate gives the known complexes cis-[M(NO)2(S2CNEt2)2](M = Mo or W), whereas, reaction with acetylacetone–Na2CO3 gives the new compounds cis-[M(NO)2(acac)2](M = Mo or W).

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Article information

DOI
https://doi.org/10.1039/DT9720002629
Article type
Paper

J. Chem. Soc., Dalton Trans., 1972, 2629-2631

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Cationic transition metal complexes. Part IV. Molybdenum and tungsten dinitrosyl complexes

M. Green and S. H. Taylor, J. Chem. Soc., Dalton Trans., 1972, 2629 DOI: 10.1039/DT9720002629

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