Ethylenebis(diphenylphosphine oxide) complexes of divalent cobalt, nickel, and copper have been prepared and studied by magnetic and spectroscopic techniques. Polymeric pseudotetrahedral 1 : 1 adducts are formed by cobalt and copper halides in which the ligand is non-chelating. The 2 : 1 perchlorate complexes of cobalt and nickel contain co-ordinated solvent and are both octahedral.
B. J. Brisdon, J. Chem. Soc., Dalton Trans., 1972, 2247 DOI: 10.1039/DT9720002247
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