The 119Sn Mössbauer parameters for the solid phases isolated from the aqueous and molten MX–SnX2 systems are reported (M = Na, K, Rb, Cs, NH4; X = Cl, Br). Data for complexes of types MSnX3, MX,MSnX3, and MSn2X5 are discussed in terms of the likely environments for tin(II) and of the use of tin bonding orbitals in complex formation.
S. R. A. Bird, J. D. Donaldson and J. Silver, J. Chem. Soc., Dalton Trans., 1972, 1950 DOI: 10.1039/DT9720001950
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