Issue 17, 1972

Hexahydrido-complexes of tungsten containing dimethylphenylphosphine or diethylphenylphosphine as ligands

Abstract

Reduction of trans-[WCl4(PMe2Ph)2], trans-[WBr4(PMe2Ph)2] or [WCl4(PMe2Ph)3] with sodium borohydride gives [WH6(PMe2Ph)3], which is fluxional, Impure [WH6(PEt2Ph)3] was similarly prepared. I.r. and 1H n.m.r. data are given and discussed.

Article information

Article type
Paper

J. Chem. Soc., Dalton Trans., 1972, 1910-1911

Hexahydrido-complexes of tungsten containing dimethylphenylphosphine or diethylphenylphosphine as ligands

J. R. Moss and B. L. Shaw, J. Chem. Soc., Dalton Trans., 1972, 1910 DOI: 10.1039/DT9720001910

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