Issue 17, 1972

Bicyclo[3,3,0]octa-2,4-dien-1-yl(cyclo-octa-1,5-diene)cobalt

Abstract

Cyclo-octenylcyclo-octa-1,5-dienecobalt Co(C8H13)(C8H12)(I) reacts with cyclo-octa-1,5-diene to give the title complex (II). An intermediate 1–3-η-cyclo-octa-1,5-dienyl(cyclo-octa-1,5-diene)cobalt complex Co-(C8H11)(C8H12)(III) has been isolated and characterised. A possible reaction path of the dehydrogenative ring closure of (I) to (II) is discussed.

Article information

Article type
Paper

J. Chem. Soc., Dalton Trans., 1972, 1879-1882

Bicyclo[3,3,0]octa-2,4-dien-1-yl(cyclo-octa-1,5-diene)cobalt

S. Otsuka and T. Taketomi, J. Chem. Soc., Dalton Trans., 1972, 1879 DOI: 10.1039/DT9720001879

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