Structural and mechanistic studies of co-ordination compounds. Part V. The preparation, aquation, and base hydrolysis of octahedral cobalt(III)–amine complexes containing isothiocyanate as an orienting ligand

K. S. Mok; C. K. Poon; H. W. Tong

doi:10.1039/DT9720001701

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Structural and mechanistic studies of co-ordination compounds. Part V. The preparation, aquation, and base hydrolysis of octahedral cobalt(III)–amine complexes containing isothiocyanate as an orienting ligand

K. S. Mok, C. K. Poon and H. W. Tong

Abstract

The prepration and characterization of trans-[Co(NH₃)₄(NCS)Cl]⁺ cation is described. The kinetics of the aquation and base hydrolysis of this complex cation and those of trans-[Co(cyclam)(NCS)Cl]⁺ have been studied over a range of temperature. These results are discussed in terms of the influence of nephelaxetic effects of these amine ligands on the central cobalt(III) ion.

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DOI: https://doi.org/10.1039/DT9720001701
Article type: Paper

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J. Chem. Soc., Dalton Trans., 1972, 1701-1704

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Structural and mechanistic studies of co-ordination compounds. Part V. The preparation, aquation, and base hydrolysis of octahedral cobalt(III)–amine complexes containing isothiocyanate as an orienting ligand

K. S. Mok, C. K. Poon and H. W. Tong, J. Chem. Soc., Dalton Trans., 1972, 1701 DOI: 10.1039/DT9720001701

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Journal of the Chemical Society, Dalton Transactions

Structural and mechanistic studies of co-ordination compounds. Part V. The preparation, aquation, and base hydrolysis of octahedral cobalt(III)–amine complexes containing isothiocyanate as an orienting ligand

Abstract

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Download Citation

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Structural and mechanistic studies of co-ordination compounds. Part V. The preparation, aquation, and base hydrolysis of octahedral cobalt(III)–amine complexes containing isothiocyanate as an orienting ligand

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