Issue 15, 1972

Evidence of a crystalline phase transition of decacarbonyldirhenium

Abstract

The thermal behaviour of decacarbonyldirhenium has been investigated. A reversible crystalline phase transition appears at 92 °C in all atmospheres studied: nitrogen, air, argon, and oxygen. A Debye–Scherrer X-ray diffraction diagram of the new crystalline phase is submitted, and an interpretation of the transition is suggested.

Article information

Article type
Paper

J. Chem. Soc., Dalton Trans., 1972, 1626-1627

Evidence of a crystalline phase transition of decacarbonyldirhenium

P. Lemoine, M. Gross and J. Boissier, J. Chem. Soc., Dalton Trans., 1972, 1626 DOI: 10.1039/DT9720001626

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