The complexes (π-C5H5)2M(SnX3)X, where M = Mo or W and X = Cl or Br are described. They react with chlorine or bromine respectively forming the salts [(π-C5H5)2MX2]+SnX3–. The complexes (π-C5H5)2M![[double bond, length as m-dash]](https://www.rsc.org/images/entities/char_e001.gif)
O (M = Mo or W). (π-C5H5)2MoSO4, and (π-C5H5)2MoS2O3 have also been prepared.
M. L. H. Green, A. H. Lynch and M. G. Swanwick, J. Chem. Soc., Dalton Trans., 1972, 1445 DOI: 10.1039/DT9720001445
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