Issue 13, 1972
From the journal:

Journal of the Chemical Society, Dalton Transactions

Perhalogenated polyboron and silicon–boron analogues of borane

R. W. Kirk,   D. L. Smith,   W. Airey  and  P. L. Timms  

Abstract

The compound B8F12, prepared by disproportionation of of F2BBFBF2, has been characterised. It is believed to be a structural analogue of diborane. It has been treated with electron-pair donors to give complexes (BF2)3BL (L = CO, PF3, PCl3, PH3, AsH3, and SMe2). Related complexes have been made from SiCl2 or SiF2 and diboron tetrahalides in the presence of CO or PF3, and the compounds (SiCl3)2(BCl2)BCO and (SiCl3)2(BF2)BPF3 have been characterised.

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Article information

DOI
https://doi.org/10.1039/DT9720001392
Article type
Paper

J. Chem. Soc., Dalton Trans., 1972, 1392-1396

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Perhalogenated polyboron and silicon–boron analogues of borane

R. W. Kirk, D. L. Smith, W. Airey and P. L. Timms, J. Chem. Soc., Dalton Trans., 1972, 1392 DOI: 10.1039/DT9720001392

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