The i.r. and Raman spectra of Co(π-C3H5)(CO)3 are reported, and an assignment proposed. The vibrations of the Co(CO)3 portion of the molecule can be assigned assuming a [local symmetry] of C3v, in contrast to the molecule Mn(π-C3H5)(CO)4, where the overall symmetry had to be used.
D. C. Andrews and G. Davidson, J. Chem. Soc., Dalton Trans., 1972, 1381 DOI: 10.1039/DT9720001381
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