SCHEDULED MAINTENANCE
The complexes Ru(NCS)(CO)(NO)(PPh3)2(I) and Ru(O2)(NCS)(NO)(PPh3)2(II) have been shown to be efficient catalysts for the homogeneous oxidation of PPh3 to OPPh3. In xylene solution rate α[catalyst] and rate–1α[PPh3]–1. The rate depends on p(O2) for (I) but not for (II). A mechanism is suggested which accommodates these facts.
B. W. Graham, K. R. Laing, C. J. O'Connor and W. R. Roper, J. Chem. Soc., Dalton Trans., 1972, 1237 DOI: 10.1039/DT9720001237
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