The nature of the triscarbonatocobaltate(III) species in aqueous solution and in some salts has been studied by i.r. spectroscopy. The presence of the trischelated species [Co(CO3)3]3– is demonstrated by an optical resolution, using (+)[Co(en)3]3+.
R. D. Gillard, P. R. Mitchell and M. G. Price, J. Chem. Soc., Dalton Trans., 1972, 1211 DOI: 10.1039/DT9720001211
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