The crystal structures of the tetraphenyl derivatives of the Group IVB elements (MPh4; M = C, Si, Ge, or Sn) are compared. All are tetragonal, Z= 2, space-group P![[4 with combining macron]](https://www.rsc.org/images/entities/char_0034_0304.gif)
21c, with symmetry. Parameters obtained from a new determination of the crystal structure of SiPh4 are in good agreement with those published earlier.
P. C. Chieh, J. Chem. Soc., Dalton Trans., 1972, 1207 DOI: 10.1039/DT9720001207
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