Mössbuer spectral parameters and paramagnetic susceptibilites have been measured for four tris(monothio-β-diketonato)iron(III) complexes. The results are interpreted in terms of a thermal equilibrium between sextet and doublet electronic states. In favourable case, superimposed spectra are observed in which both spin states can be recognised.
M. Cox, J. Darken, B. W. Fitzsimmons, A. W. Smith, L. F. Larkworthy and K. A. Rogers, J. Chem. Soc., Dalton Trans., 1972, 1192 DOI: 10.1039/DT9720001192
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