Issue 10, 1972

Crystal and molecular structure of tetramethylformamidiniumphosphonate, [Me2N]2CPO3H

Abstract

Crystals of the title compound, an inner salt [Me2N]2CPO3H, are monoclinic, space-group P21/c with a= 8·415 b= 7·719, c= 12·719 Å, β= 91·5°, Z= 4. The structure was solved by direct methods from diffractometer data for 1414 planes, and refined by least squares to a final R of 0·047. The (PO3H)- group is linked to the central carbon atom of the (Me2N:C·NMe2)+ group by a P–C bond of 1·890(2)Å. The central carbon atom and the two nitrogen atoms of the formamidinium group all adopt planar configurations.

Article information

Article type
Paper

J. Chem. Soc., Dalton Trans., 1972, 1048-1051

Crystal and molecular structure of tetramethylformamidiniumphosphonate, [Me2N]2CPO3H

J. J. Daly, J. Chem. Soc., Dalton Trans., 1972, 1048 DOI: 10.1039/DT9720001048

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