Infrared and Raman spectra between 450 and 200 cm–1 of a large series of adducts of aryl and alkyl sulphoxides with mercury(II) chloride, R1R2SO,mHgCl2, m= 1, 1·5, and 2 have been recorded. The characteristic frequencies of groups Cl–Hg–Cl and Hg–O have been assigned. Spectral features are correlated with the molecular structures of adducts with different ratios of complexation.
P. Biscarini, L. Fusina and G. D. Nivellini, J. Chem. Soc., Dalton Trans., 1972, 1003 DOI: 10.1039/DT9720001003
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