The rate of racemisation of the trisoxalatochromium(III) anion shows a very high order of dependence on acid concentration. We present data for catalysis of the reaction by HClO4, HCl, and H2SO4. An A-1 mechanism for the racemisation is proposed.
A. L. Odell, R. W. Olliff and D. B. Rands, J. Chem. Soc., Dalton Trans., 1972, 752 DOI: 10.1039/DT9720000752
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