The rate of ligand substitution reaction in trans-[lr(en)2Cl2]+ by Cl–, Br–, and NO2– has been investigated in water, water–dioxan, and water–ethanol (up to 60% v/v dioxan or ethanol). The effects of variation of ligand, ion concentration, solvent, and temperature are discussed. The results show ion-pair formation in all of the cases studied.
J. Burgess, E. R. Gardner and F. M. Mekhail, J. Chem. Soc., Dalton Trans., 1972, 487 DOI: 10.1039/DT9720000487
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