The isolation of stable complexes (cp)2M(Cl)M1Ph3(cp =π-C5H5; M = Zr or Hf; M1= Si or Ge) is described. Spectroscopic data and some M–Si cleavage reactions are reported. The complexes are of interest as d° complexes having metal–metal bonds and with the transition metal in a high (+4) oxidation state.
B. M. Kingston and M. F. Lappert, J. Chem. Soc., Dalton Trans., 1972, 69 DOI: 10.1039/DT9720000069
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