Jump to main content
Jump to site search

Volume 54, 1972
Previous Article Next Article

High energy photoelectron spectroscopy of transition metal complexes. Part 1.—Bonding in substituted and unsubstituted first row carbonyls

Abstract

Core electron binding energies of a series of substituted and unsubstituted transition metal carbonyls are reported and interpreted using both ab initio and approximate molecular orbital calculations. The ESCA chemical shifts observed upon substitution are well reproduced by such calculations, although the rather poor prediction of the change in CO core binding energies on complex formation, together with the observation of unusually intense satellite peaks in the photoelectron spectra of the carbonyls suggests that orbital relaxation may be greater in complexed than in free CO.

Back to tab navigation

Article type: Paper
DOI: 10.1039/DC9725400219
Citation: Faraday Discuss. Chem. Soc., 1972,54, 219-226
  •   Request permissions

    High energy photoelectron spectroscopy of transition metal complexes. Part 1.—Bonding in substituted and unsubstituted first row carbonyls

    M. Barber, J. A. Connor, M. F. Guest, M. B. Hall, I. H. Hillier and W. N. E. Meredith, Faraday Discuss. Chem. Soc., 1972, 54, 219
    DOI: 10.1039/DC9725400219

Search articles by author

Spotlight

Advertisements