Photoionization of CO2 and COS by He and Ne resonance lines, and of CS2 by He, Ne and Ar resonance lines gives photoelectron spectra which show that vibrational levels of the ground ionic state of these species can be populated by an autoionization process, when the photons used have the suitable energy to bring these molecules in superexcited states.
P. Natalis, J. Delwiche and J. E. Collin, Faraday Discuss. Chem. Soc., 1972, 54, 98 DOI: 10.1039/DC9725400098
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