Known limitations of the Stuckelberg-Landau-Zener formula are described in terms of an analogy between the curve-crossing and barrier penetration problems. Available perturbation and other correction methods are reviewed. Applications of the theory to the interpretation of molecular predissociation, collision cross-section and kinetic rate constant measurements are outlined.
M. S. Child, Faraday Discuss. Chem. Soc., 1972, 53, 18 DOI: 10.1039/DC9725300018
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...