Issue 21, 1972

Isolation of a new intermediate complex in the nitrogen-fixing system (π-C5H5)2TiCl + MeMgI + N2

Abstract

A binuclear complex cp2TiN2Ticp2 has been isolated at low temperature in the system cp2TiCI + MeMgI + N2(cp =π-C5H5); it is apparently a di-imide derivative, and initially froms N2H2 when decomposed with HCl.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1972, 1178a-1178a

Isolation of a new intermediate complex in the nitrogen-fixing system (π-C5H5)2TiCl + MeMgI + N2

Yu. G. Borodko, I. N. Ivleva, L. M. Kachapina, S. I. Salienko, A. K. Shilova and A. E. Shilov, J. Chem. Soc., Chem. Commun., 1972, 1178a DOI: 10.1039/C3972001178A

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