Irradiation of benzene solutions of the dihydride (π-C5H5)2WH2 with a mercury lamp (366 nm) gives the phenyl hydride (π-C5H5)2WHPh in high yield and further evidence suggests the reaction proceeds via tungstenocene (π-C5H5)2W as an intermediate.
C. Giannotti and M. L. H. Green, J. Chem. Soc., Chem. Commun., 1972, 1114b DOI: 10.1039/C3972001114B
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