SCHEDULED MAINTENANCE
1,4-Hydrogen migration in triplet 3-methylbut-1-ene produces the triplet 1,2-dimethyl-1,3-trimethylene biradical which can subsequently cyclise to trans- and cis,2-dimethylcyclopropane in a ratio strongly dependent on its internal vibrational energy.
D. C. Montague, J. Chem. Soc., Chem. Commun., 1972, 615b DOI: 10.1039/C3972000615B
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