Treatment of 6-amino-5-nitrosopyrimidines with the Vilsmeier reagent (dimethylformamide and phosphorus oxychloride) afforded in general the respective 8-dimethylaminopurines; treatment of 6-amino-4-hydroxy-2-methyl-5-nitrosopyrimidine gave 2-chloromethyl-8-dimethylamino-6-hydroxypurine.
F. Yoneda, T. Matsumura and K. Senga, J. Chem. Soc., Chem. Commun., 1972, 606a DOI: 10.1039/C3972000606A
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