Formation of the carbene complexes [Mn-([graphic omitted])(CO)5]PF6, cis-[MnCl([graphic omitted])(CO)4], fac-[MnCl(PPh3)([graphic omitted])(CO)3], and cis-[MnI([graphic omitted]H2)(CO)4] is described; an X-ray crystallographic study confirms the identity of the second complex.
M. Green, J. R. Moss, I. W. Nowell and F. G. A. Stone, J. Chem. Soc., Chem. Commun., 1972, 1339 DOI: 10.1039/C39720001339
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