Co-ordination of a cis-divinylcyclopropane to rhodium(I) inhibits Cope rearrangement; at elevated temperatures a vinylcyclopropane–cyclopentene isomerisation is the dominant reaction course.
V. Aris, J. M. Brown and B. T. Golding, J. Chem. Soc., Chem. Commun., 1972, 1206 DOI: 10.1039/C39720001206
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