The reaction of hexaborane(10) with ennea-carbonyldi-iron gives the novel complex µ-Fe(CO)4–B6H10, in which the iron centre is shown to be co-ordinated to the unique basal boron–boron bond of B6H10.
A. Davison, D. D. Traficante and S. S. Wreford, J. Chem. Soc., Chem. Commun., 1972, 1155 DOI: 10.1039/C39720001155
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