Ab initio SCF-MO calculations on amino-phosphine, H2NPH2, indicate that the nitrogen atom adopts a trigonal planar geometry, as a consequence of inductive electron release from the PH2 group.
I. G. Csizmadia, A. H. Cowley, M. W. Taylor, L. M. Tel and S. Wolfe, J. Chem. Soc., Chem. Commun., 1972, 1147 DOI: 10.1039/C39720001147
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