Photolysis of steroidal β,γ-epoxyketones
Abstract
An unusual condensed phase photodecarbonylation of a steroidal 9,10-epoxy-6-ketone is reported in which hydrogen atom shifts from C-7 to C-5 and from C-8 to C-7 give rise to the main product.
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J. Chem. Soc., Chem. Commun., 1972, 1122-1123
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Photolysis of steroidal β,γ-epoxyketones
R. J. Chambers and B. A. Marples, J. Chem. Soc., Chem. Commun., 1972, 1122 DOI: 10.1039/C39720001122
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