The trienic primary product formed in the photochemical ring opening of the cyclohexadienic isodypnopinacolone follows two different photoreaction pathways: a [4π+2π] cycloaddition and a [6π+2π] reaction involving the conjugated carbonyl group.
P. Courtot and R. Pichon, J. Chem. Soc., Chem. Commun., 1972, 1103 DOI: 10.1039/C39720001103
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