The novel compounds IrX(OOBut)2(CO)L2(X = Cl; L = PPh3, AsPh3, or PPh2Me, and X = Br; L = PPh3 or AsPh3) and IrX(OOCPhMe2)2(CO)(PPh3)2(X = Cl or Br) have been isolated from the reactions of ButOOH or PhMe2COOH with the respective trans-IrX(CO)L2 complexes; the similar reaction of ButOOH with trans-IrI(CO)(PPh3)2 yields IrI2(OOBut)(CO)(PPh3)2.
B. L. Booth, R. N. Haszeldine and G. R. H. Neuss, J. Chem. Soc., Chem. Commun., 1972, 1074 DOI: 10.1039/C39720001074
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