The new thiophosphorimides P4(NMe)6Sn, with n= 1–3, have structures related to those of the series of oxides P4O7, P4O8, and P4O9; scrambling of the peripheral sulphur atoms gave equilibrated mixtures in which the inner P4(NMe)6 core is retained.
J. G. Riess and A. Wolff, J. Chem. Soc., Chem. Commun., 1972, 1050 DOI: 10.1039/C39720001050
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