The structure of a binuclear complex hydride obtained by controlled pyrolysis of Ru3(CO)9[P(OPh)3]3has been determined; unusual features include the bridging of the two metal atoms by both an OP(OPh)2 group and the phenyl ring of one of the two ortho-metallated phosphite ligands.
M. I. Bruce, J. Howard, I. W. Nowell, G. Shaw and P. Woodward, J. Chem. Soc., Chem. Commun., 1972, 1041 DOI: 10.1039/C39720001041
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