Adirubine (1a), the first example of a new series of carboxy-alkaloids with the Corynanthe skeleton, has been isolated from Adina rubescens and its structure determined from chemical and spectral data.
R. T. Brown, C. L. Chapple and G. K. Lee, J. Chem. Soc., Chem. Commun., 1972, 1007 DOI: 10.1039/C39720001007
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