Chloroform-iminium or -amidinum chlorides oxidatively add to RhI or PtII compounds to give RhIII or PtIV carbene complexes; of particular interest are the Cr0, Fe0, RhIII, IrIII, and PtIV complexes of the secondary carbene CHNMe2, in which the hydrogen atom attached to C(carbene) is deshielded (τ–1·2 to +0·9).
B. Cetinkaya, M. F. Lappert and K. Turner, J. Chem. Soc., Chem. Commun., 1972, 851 DOI: 10.1039/C39720000851
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