Issue 14, 1972

Stereochemistry of the ring-opening of an activated vinylcyclopropane

Abstract

Optically active dimethyl 2-vinylcyclopropane-1,1-dicarboxylate reacts with pyrolidine with clean inversion of configuration at C(5); its reaction with enamines appears to involve prior cleavage of the C(3)–C(5) bond.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1972, 821-822

Stereochemistry of the ring-opening of an activated vinylcyclopropane

S. Danishefsky and G. Rovnyak, J. Chem. Soc., Chem. Commun., 1972, 821 DOI: 10.1039/C39720000821

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